Orientation effects in reactions of allenyl cations with styrene

Mayr, Herbert and Grubmüller, Bärbel and Halberstadt, Inge K. (1979): Orientation effects in reactions of allenyl cations with styrene. In: Tetrahedron Letters, Vol. 20, No. 20: pp. 1749-1752

Abstract

Allenyl cations, generated from allenyl or alkynyl halides and Ag+, attack styrene at the side chain or at the aromatic nucleus. The allenyl/alkynyl product ratio is dependent on the structure of the precursor halide except for highly substituted systems.

• Item Type: Article
• Collections: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry