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Sünkel, Karlheinz; Schloter, Klaus; Beck, Wolfgang; Ackermann, Klaus and Schubert, Ulrich (1983): Metallorganische Lewis-Säuren. Metallkomplexe mit schwach koordinierten Liganden. XI. Acetylverbrückte kationische Komplexe von Molybdän, Eisen und Mangan; Struktur von [(π-C5H5)(CO)2Mo(μ2-η2-CH3CO)Mo(CO)2(π-C5H5]+ BF4−. In: Journal of Organometallic Chemistry, Vol. 241, No. 3: pp. 333-342.

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DOI: http://dx.doi.org/10.1016/S0022-328X(00)98527-9

Abstract

Die Tetrafluoroborato- und Hexafluoroantimonato-Komplexe (π-C5H5)(CO)3MoX (X = FBF3, FSbF5) setzen sich mit (π-C5H5)(CO)3MoCH3, (π-C5H5)(CO)2FeCH3 oder (π-C5H5)(CO)2FeCOCH3 und cis-, trans-Ph3P(CO)4MnCOCH3 zu [(π-C5H5)(CO)2Mo(μ2-η2-COCH3)Mo(CO)2(π-C5H5)]+ BF4− (I), [(π-C5H5)(CO)2Fe - C(CH3)O-Mo(CO)3(π-C5H5)]+ SbF6− (II) und [(Ph3P)(CO)4Mn-C(CH3)O-Mo(CO)3(π-C5H5)]+ BF4− (III) um.

Item Type:Article
Subjects:Chemistry and Pharmacy
Dewey Classification:600 Natural sciences and mathematics
600 Natural sciences and mathematics > 540 Chemistry and allied sciences
URN:urn:nbn:de:bvb:19-epub-5399-0
ID Code:5399
Deposited On:05. Aug 2008 15:44
Last Modified:28. Jun 2010 14:57
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