Logo
DeutschClear Cookie - decide language by browser settings
Sünkel, Karlheinz and Motz, Doris (1988): Komplexchemie perhalogenierter Cyclopentadiene und Alkine. I. Metallierung von (C5Cl4Br)Mn(CO)3 und Umsetzungen mit Elektrophilen. In: Chemische Berichte, Vol. 121, No. 4: pp. 799-801
[img]
Preview

PDF

18MB

Abstract

Coordination Chemistry of Perhalogenated cyclopentadienes and Alkynes, I. - metalation of (C5Cl4Br)Mn(CO)3 and Reactions with Electrophiles Lithiation of (C5Cl4Br)Mn(CO)3 with n-butyllithium gives the isolable, but very air-sensitive (C5Cl4Li)Mn(CO)3 (2), which reacts with a series of electrophiles to yield (C5Cl4Br)Mn(CO)3 (3), where E = H, Me, SiR3, CO2R or SR.