Komplexchemie perhalogenierter Cyclopentadiene und Alkine

Sünkel, Karlheinz (1988): Komplexchemie perhalogenierter Cyclopentadiene und Alkine. III. Reaktion von Pt(PPh3)2(C2H4) mit Monofluoracetylen und Dichloracetylen. Kristallstruktur von Pt(PPh3)2(Cl)(CCCl). In: Journal of Organometallic Chemistry, Vol. 348, No. 1: C12-C14

Abstract

Pt(PPh3)2(C2H4) reacts with monofluoroacetylene to give the π-complex Pt(PPh3)2(FCCH), and with dichloroacetylene under oxidative addition to yield Pt(PPh3)2(Cl)(ClCCl), the structure of which was determined by X-ray crystallography.

• Item Type: Article
• Collections: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry