Komplexchemie perhalogenierter Cyclopentadiene und Alkine, VII

Sünkel, Karlheinz (1991): Komplexchemie perhalogenierter Cyclopentadiene und Alkine, VII. Darstellung einiger Tetrachlormetallole von Cobalt, Rhodium und Iridium; Struktur eines Iridacyclopentadien-Derivats. In: Chemische Berichte, Vol. 124, No. 11: pp. 2449-2451

Abstract

Coordination Chemistry of Perhalogenated Cyclopentadienes and Alkynes, VII1). - Synthesis of Several Tetrachlorometalloles of Cobalt, Rhodium, and Iridium; Structure of a Iridacyclopentadiene Derivative The reaction of dichloroethyne with CpCo(PPh3)2, RhCl(EPh3)3 (E = P, As, Sb), and IrCl(N2)(PPh3)2 leads to the formation of complexes containing a tetrachloro-1-metallacyclopentadiene unit. The crystal-structure determination of (Ph3P)2(Cl)- is reported.

• Item Type: Article
• Collections: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry
• Signature: Chem. 26 h-124,9/12