ORCID: https://orcid.org/0000-0002-4920-0957; Leitz, Dominik; Bockmair, Valentin ORCID: https://orcid.org/0009-0007-4048-6374 und Kornath, Andreas J. ORCID: https://orcid.org/0000-0002-7307-4516
(2025):
Monoprotonated species of 2-aminomalonyl difluoride, [C3H4F2NO2][H2F3].
In: Acta Crystallographica Section C Structural Chemistry, Vol. 81, No. 2: pp. 77-81
[PDF, 2MB]
Abstract
The monoprotonated species of 2-aminomalonyl difluoride, namely, 1,3-difluoro-1,3-dioxopropan-2-aminium dihydrogen trifluoride, [C3H4F2NO2][H2F3],was synthesized from sulfur tetrafluoride in anhydrous hydrogen fluoride (aHF) with [NH4][C3H5NO4] as the starting material. The solvent was removed and the salt was dissolved in aHF and crystallized. In the solid state, the three-dimensional network is built by medium–strong N—H...F hydrogen bonds and C...F contacts. This is the first structure determination of an aminoacyl difluoride and the second of an aminoacyl fluoride.
| Item Type: | Journal article |
|---|---|
| Faculties: | Chemistry and Pharmacy > Department of Chemistry |
| Subjects: | 500 Science > 540 Chemistry |
| URN: | urn:nbn:de:bvb:19-epub-126551-4 |
| ISSN: | 2053-2296 |
| Language: | English |
| Item ID: | 126551 |
| Date Deposited: | 13. Jun 2025 05:55 |
| Last Modified: | 13. Jun 2025 05:55 |
| DFG: | Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - 444769550 |
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