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Stock, Norbert; Schnick, Wolfgang (1997): Trisodium Trimetaphosphimate Monohydrate. In: Acta Crystallographica, C, Vol. 53, Nr. 5: S. 532-534
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Abstract

The trimetaphosphimate anion (PO2NH)33- in trisodium cyclo-tri--imidotriphosphate monohydrate, Na3(PO2NH)3.H2O, exhibits a chair conformation. Two trimetaphosphimate rings are linked to each other by six N-HO hydrogen bonds forming pairs. These units are interconnected by O-HO hydrogen bonds through water molecules forming columns.