Manolikakes, Sophia M.; Jaric, Milica; Karaghiosoff, Konstantin; Knochel, Paul
Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl center dot BF3 and their addition to aromatic aldehydes and activated ketones.
In: Chemical Communications, Vol. 49, Nr. 21: S. 2124-2126
Treatment of pyridines, quinoline and methylthiopyrazine with the frustrated Lewis pair TMPMgCl center dot BF3 (1) leads to organotrifluoro borates which react readily with a variety of aromatic aldehydes in the absence of a transition metal catalyst.