|Mayr, Herbert and Pock, Rudolf (1986): Electrophilic attack at allylsilanes. A quantitative determination of the β-silyl effect. In: Tetrahedron, Vol. 42, No. 15: pp. 4211-4214|
The relative reactivities of allylsilanes and alkenes towards diarylmethyl cations have been determined by competition experiments. Introduction of a β-trimethylsilyl group increases the reactivity of propene towards the diphenylmethyl cation by a factor of 30700.
|Collections:||Chemistry and Pharmacy|
|Subjects:||500 Science > 540 Chemistry|
|Deposited On:||20. May 2008 11:52|
|Last Modified:||08. Jan 2013 16:08|