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Music, Arif; Baumann, Andreas N.; Boser, Florian; Müller, Nicolas; Matz, Florian; Jagau, Thomas C. and Didier, Dorian (2021): Photocatalyzed Transition-Metal-Free Oxidative Cross-Coupling Reactions of Tetraorganoborates**. In: Chemistry-A European Journal, Vol. 27, No. 13: pp. 4322-4326

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Readily accessible tetraorganoborate salts undergo selective coupling reactions under blue light irradiation in the presence of catalytic amounts of transition-metal-free acridinium photocatalysts to furnish unsymmetrical biaryls, heterobiaryls and arylated olefins. This represents an interesting conceptual approach to forge C-C bonds between aryl, heteroaryl and alkenyl groups under smooth photochemical conditions. Computational studies were conducted to investigate the mechanism of the transformation.

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