Reactivities of allenic and olefinic Michael acceptors towards phosphines

An, Feng; Jangra, Harish; Wei, Yin; Shi, Min; Zipse, Hendrik und Ofial, Armin R. (21. Februar 2022): Reactivities of allenic and olefinic Michael acceptors towards phosphines. In: Chemical Communications, Bd. 58, Nr. 20: S. 3358-3361

Abstract

The kinetics of the reactions of tributylphosphine with allenic and olefinic Michael acceptors in dichloromethane at 20 °C was followed by photometric and NMR spectroscopic methods. Combination with DFT-calculated methyl anion affinities revealed the relevance of retroaddition barriers in phosphine-catalysed reactions when mixtures of allenic and olefinic substrates are used.

• Dokumententyp: Zeitschriftenartikel
• Publikationsform: Publisher's Version
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 1359-7345
• Sprache: Englisch
• DFG: Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - 410831260