Li, Le; Hsu, Jer-Ray; Zhao, Hongqing und Ofial, Armin R.
ORCID: https://orcid.org/0000-0002-9600-2793
(26. January 2023):
Nucleophilicities of Cyclic α-Diazo Carbonyl Compounds.
In: European Journal of Organic Chemistry, Vol. 26, No. 10, e202300005
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Abstract
The kinetics of the reactions of cyclic α-diazo carbonyl compounds with electrophilic benzhydrylium ions were evaluated to determine the Mayr reactivity descriptors N (and sN) of the nucleophiles. Interestingly, the thus obtained N scale also reflects relative reactivities of the diazo compounds in 1,3-dipolar cycloadditions with dimethyl acetylenedicarboxylate.
| Item Type: | Journal article |
|---|---|
| Form of publication: | Publisher's Version |
| Faculties: | Chemistry and Pharmacy > Department of Chemistry |
| Subjects: | 500 Science > 540 Chemistry |
| URN: | urn:nbn:de:bvb:19-epub-104427-5 |
| ISSN: | 1434-193X |
| Language: | English |
| Item ID: | 104427 |
| Date Deposited: | 18. Jul 2023 07:03 |
| Last Modified: | 04. Jan 2024 11:56 |
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