Abstract
[Li{C-5(CN)(5)}(H2O)] was prepared by salt metathesis between LiCl and [Ag{C-5(CN)(5)}], followed by recrystallization from methanol. The compound crystallizes in the orthorhombic space group Pnma and forms a coordination polymer. Three cyano substituents in 1,2,3 position coordinate to three different lithium ions forming a ribbon structure with adjacent 14-membered rings, while the remaining two cyano groups act as hydrogen bond acceptors towards two water hydrogen atoms of a neighboring ribbon. As a consequence, a wavy sheet structure results.
Dokumententyp: | Zeitschriftenartikel |
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Fakultät: | Chemie und Pharmazie > Department Chemie |
Themengebiete: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
ISSN: | 0044-2313 |
Sprache: | Englisch |
Dokumenten ID: | 107011 |
Datum der Veröffentlichung auf Open Access LMU: | 11. Sep. 2023, 13:46 |
Letzte Änderungen: | 11. Sep. 2023, 13:46 |
DFG: | Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - 491502892 |