Helical Anthracene-Ethyne-Based MOF-74 Analogue

Scheurle, Patricia I.; Maehringer, Andre; Haug, Tabea; Biewald, Alexander; Axthammer, Daniel; Hartschuh, Achim; Harms, Lena; Wittstock, Gunther; Medina, Dana D. und Bein, Thomas (2022): Helical Anthracene-Ethyne-Based MOF-74 Analogue. In: Crystal Growth & Design, Bd. 22, Nr. 5: S. 2849-2853

Abstract

A flexible, electro n-rich building block was integrated into the backbone of a metal-organic framework with a MOF-74 topology. The building block comprises a central anthracene core connected to acetylene groups. Solvothermal synthesis with Mn2+ yields a highly crystalline anthracene-ethyne-based MOF-74 structure. It shows an unusual helical rod-like morphology, exhibiting visible light absorption and photo-luminescence.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 1528-7483
• Sprache: Englisch