Photomemristive sensing via charge storage in 2D carbon nitrides

Gouder, Andreas; Jimenez-Solano, Alberto; Vargas-Barbosa, Nella M.; Podjaski, Filip und Lotsch, Bettina V. (2022): Photomemristive sensing via charge storage in 2D carbon nitrides. In: Materials Horizons, Bd. 9, Nr. 7

Abstract

Photomemristive sensors have the potential to innovate current photo-electrochemical sensors by incorporating new sensing capabilities including non-invasive, wireless and time-delayed (memory) readout. Here we report the charge storing 2D carbon nitride potassium poly(heptazine imide), K-PHI, as a direct photomemristive sensing platform by capitalizing on K-PHI's visible light bandgap, large oxidation potential, and intrinsic optoionic charge storage properties. Utilizing the light-induced charge storage function of K-PHI nanosheets, we demonstrate memory sensing via charge accumulation and present potentiometric, impedimetric and coulometric readouts to write/erase this information from the material, with no additional reagents required. Additionally, wireless colorimetric and fluorometric detection of the charging state of K-PHI nanoparticles is demonstrated, enabling the material's use as particle-based autonomous sensing probe in situ. The various readout options of K-PHI's response enable us to adapt the sensitivities and dynamic ranges without modifying the sensing platform, which is demonstrated using glucose as a model analyte over a wide range of concentrations (50 mu M to 50 mM). Since K-PHI is earth abundant, biocompatible, chemically robust and responsive to visible light, we anticipate that the photomemristive sensing platform presented herein opens up memristive and neuromorphic functions.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 2051-6347
• Sprache: Englisch
• DFG: Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - 390776260