ORCID: https://orcid.org/0000-0002-4920-0957; Leitz, Dominik; Bockmair, Valentin ORCID: https://orcid.org/0009-0007-4048-6374 und Kornath, Andreas J. ORCID: https://orcid.org/0000-0002-7307-4516
(2025):
Monoprotonated species of 2-aminomalonyl difluoride, [C3H4F2NO2][H2F3].
In: Acta Crystallographica Section C Structural Chemistry, Bd. 81, Nr. 2: S. 77-81
[PDF, 2MB]
Download (2MB)
Abstract
The monoprotonated species of 2-aminomalonyl difluoride, namely, 1,3-difluoro-1,3-dioxopropan-2-aminium dihydrogen trifluoride, [C3H4F2NO2][H2F3],was synthesized from sulfur tetrafluoride in anhydrous hydrogen fluoride (aHF) with [NH4][C3H5NO4] as the starting material. The solvent was removed and the salt was dissolved in aHF and crystallized. In the solid state, the three-dimensional network is built by medium–strong N—H...F hydrogen bonds and C...F contacts. This is the first structure determination of an aminoacyl difluoride and the second of an aminoacyl fluoride.
| Dokumententyp: | Zeitschriftenartikel |
|---|---|
| Fakultät: | Chemie und Pharmazie > Department Chemie |
| Themengebiete: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| URN: | urn:nbn:de:bvb:19-epub-126551-4 |
| ISSN: | 2053-2296 |
| Sprache: | Englisch |
| Dokumenten ID: | 126551 |
| Datum der Veröffentlichung auf Open Access LMU: | 13. Jun. 2025 05:55 |
| Letzte Änderungen: | 13. Jun. 2025 05:55 |
| DFG: | Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - 444769550 |
- Dokument bearbeiten
