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Huppertz, Hubert und Schnick, Wolfgang ORCID logoORCID: https://orcid.org/0000-0003-4571-8035 (1997): Eu2Si5N8 and EuYbSi4N7. The First Nitridosilicates with a Divalent Rare Earth Metal. In: Acta crystallographica, C, Bd. 53, Nr. 12: S. 1751-1753 [PDF, 1MB]

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Abstract

The crystal structures of dieuropium penta siliconoctanitride, Eu2Si5N8, and europium ytterbium tetrasiliconheptanitride, EuYbSi4N7, are based on three-dimensional networks of corner-sharing SiN4 tetrahedra. Eu2Si5N8 is isotypic with the previously reported Sr and Ba analogues; EuYbSi4N7 is isotypic with SrYbSi4N7 and BaYbSi4N7.

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