Hinterholzinger, Florian M.; Wuttke, Stefan; Roy, Pascal; Preuße, Thomas; Schaate, Andreas; Behrens, Peter; Godt, Adelheid; Bein, Thomas (2012): Highly oriented surface-growth and covalent dye labeling of mesoporous metal-organic frameworks. In: Dalton Transactions, Vol. 41, No. 14: pp. 3899-3901 |
| 2MB |
DOI: 10.1039/c2dt12265k
External fulltext: http://pubs.rsc.org/en/content/articlepdf/2012/dt/c2dt12265k?page=search
Abstract
Mesoporous amino-functionalized metal–organic framework thin films with the UiO-68 topology were grown in a highly oriented fashion on two different self-assembled monolayers on gold. The oriented MOF films were covalently modified with the fluorescent dye Rhodamine B inside the pore system, as demonstrated with size-selective fluorescence quenching studies. Our study suggests that mesoporous metal–organic frameworks are promising hosts for the covalent attachment of numerous functional moieties in a molecularly designed crystalline environment.
Item Type: | Journal article |
---|---|
Form of publication: | Publisher's Version |
Faculties: | Chemistry and Pharmacy |
Subjects: | 500 Science > 540 Chemistry |
URN: | urn:nbn:de:bvb:19-epub-15889-0 |
Alliance/National Licence: | This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively. |
Language: | English |
ID Code: | 15889 |
Deposited On: | 11. Jul 2013 12:59 |
Last Modified: | 04. Nov 2020 12:57 |
Repository Staff Only: item control page