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Kuhn, Alexander; Gerbig, Oliver; Zhu, Changbao; Falkenberg, Frank; Maier, Joachim; Lotsch, Bettina V. (2014): A new ultrafast superionic Li-conductor: ion dynamics in Li11Si2PS12 and comparison with other tetragonal LGPS-type electrolytes. In: Physical Chemistry Chemical Physics, Vol. 16, No. 28: pp. 14669-14674




We report on a new ultrafast solid electrolyte of the composition Li11Si2PS12, which exhibits a higher room-temperature Li ion diffusivity than the present record holder Li10GeP2S12. We discuss the high-pressure synthesis and ion dynamics of tetragonal Li11Si2PS12, and comparison is made with our investigations of related members of the LMePS family, i.e. electrolytes of the general formula Li11-xMe2-xP1+xS12 with Me = Ge, Sn : Li10GeP2S12, Li7GePS8, Li10SnP2S12. The structure and dynamics were studied with multiple complementary techniques and the macroscopic diffusion could be traced back to fast Li ion hopping in the crystalline lattice. A clear correlation between the diffusivity and the unit cell volume of the LGPS-type electrolytes was observed.