
Abstract
The photoinduced dynamics of the fully halogenated cyclopentadienes C5Cl6 and C5Br6 have been investigated in solution and gas phase by femtosecond time-resolved spectroscopy. Both in solution and in gas phase, homolytic dissociation into a halogen radical and a C5X5 (X = Cl, Br) radical was observed. In liquid phase, solvent-dependent formation of charge transfer complexes between geminate radicals was observed for the first time. These complexes were found to be surprisingly stable and offered the opportunity to follow the dynamics of specific radical pairs. In the case of C5Cl6 in trichloroethanol, a reaction of the chlorine radical with molecules from the solvent cage was observed.
Item Type: | Journal article |
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Form of publication: | Publisher's Version |
Faculties: | Physics |
Subjects: | 500 Science > 530 Physics |
URN: | urn:nbn:de:bvb:19-epub-22685-3 |
ISSN: | 1463-9076 |
Alliance/National Licence: | This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively. |
Language: | English |
Item ID: | 22685 |
Date Deposited: | 04. Feb 2015, 11:23 |
Last Modified: | 08. May 2024, 08:21 |