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Manolikakes, Sophia M.; Jaric, Milica; Karaghiosoff, Konstantin; Knochel, Paul (2013): Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl center dot BF3 and their addition to aromatic aldehydes and activated ketones. In: Chemical Communications, Vol. 49, No. 21: pp. 2124-2126
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Abstract

Treatment of pyridines, quinoline and methylthiopyrazine with the frustrated Lewis pair TMPMgCl center dot BF3 (1) leads to organotrifluoro borates which react readily with a variety of aromatic aldehydes in the absence of a transition metal catalyst.