Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl center dot BF3 and their addition to aromatic aldehydes and activated ketones

Manolikakes, Sophia M.; Jaric, Milica; Karaghiosoff, Konstantin and Knochel, Paul (2013): Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl center dot BF3 and their addition to aromatic aldehydes and activated ketones. In: Chemical Communications, Vol. 49, No. 21: pp. 2124-2126

Abstract

Treatment of pyridines, quinoline and methylthiopyrazine with the frustrated Lewis pair TMPMgCl center dot BF3 (1) leads to organotrifluoro borates which react readily with a variety of aromatic aldehydes in the absence of a transition metal catalyst.

• Item Type: Journal article
• Form of publication: Publisher's Version
• Faculties: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry
• ISSN: 1359-7345
• Alliance/National Licence: This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
• Language: English