
Abstract
We present results of a comparative study of colloidal anatase titanium oxide nanorods and extremely thin atomic wires of systematically decreasing (2.6 nm down to 0.5 nm) diameter in terms of their optical absorption as well as steady-state and time-resolved photoluminescence. Steady-state photoluminescence spectra of the titania samples show three well-distinguished spectral components, which are ascribed to excitonic emission (4.26 +/- 0.2 eV), as well as radiative recombination of trapped holes with electrons from the conduction band (4.04 +/- 0.4 eV) and radiative recombination of trapped electrons with holes in the valence band (3.50 +/- 0.2 eV) in nanocrystalline anatase TiO2. Time-resolved photoluminescence measurements point out the existence of different emissive species responsible for the appearance of high-energetic and low-energetic emission peaks of TiO2 atomic wires and nanorods.
Item Type: | Journal article |
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Form of publication: | Publisher's Version |
Faculties: | Physics |
Subjects: | 500 Science > 530 Physics 500 Science > 540 Chemistry |
URN: | urn:nbn:de:bvb:19-epub-22690-5 |
ISSN: | 2040-3364 |
Alliance/National Licence: | This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively. |
Language: | English |
Item ID: | 22690 |
Date Deposited: | 04. Feb 2015, 10:20 |
Last Modified: | 08. May 2024, 08:21 |