Leupold, D.; Struck, A.; Stiel, H.; Teuchner, K.; Oberländer, S.; Scheer, Hugo
Excitated state properties of 20-chloro-chlorophyll a.
In: Chemical Physics Letters, Vol. 170: pp. 478-484
The excited-state and lasing properties of 20-chloro-chlorophyll a in ether solution were compared to those of chlorophyll a. Desactivation parameters and cross-sections were obtained from non-linear absorption spectroscopy in combination with a physico-mathematical methods package. The Cl substituent at C-20 (1) increases both intersystem crossing and internal conversion, (2) produces a blue-shift of the S1 absorption spectrum, and (3) leads to pronounced photochemistry.