Inorganic Amino-Nitro-Guanidinium Derivatives

Fischer, Niko; Klapötke, Thomas M.; Lux, Karin; Martin, Franz A. and Stierstorfer, Jörg (2012): Inorganic Amino-Nitro-Guanidinium Derivatives. In: Crystals, Vol. 2, No. 2: pp. 675-689

Abstract

1-Amino-3-nitroguanidine (ANQ, 1) was synthesized by hydrazinolysis of nitroguanidine (NQ) with hydrazine hydrate. Four different amino-nitroguanidinium salts (chloride (2), bromide (3), iodide (4) and sulfate (5)) were synthesized and structurally characterized by low-temperature X-ray diffraction. The halides 2–4 could only be obtained crystalline as monohydrates. In addition, they were characterized by NMR and vibrational spectroscopy, elemental analysis and the sensitivities towards impact, friction and electrostatic discharge were determined. The compounds can be used in silver (AgX, X = Cl, Br, I) and barium (BaSO4) based metathesis reactions in order to form more complex salts of 1-amino-nitroguanidine.

• Item Type: Journal article
• Form of publication: Publisher's Version
• Keywords: nitroguanidine; crystal structures; halides; sulfates
• Faculties: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry
• ISSN: 2073-4352
• Language: English