STUDIES ON PLANT BILE PIGMENTS-6. PHOTOCHEMICALLY ASSISTED REACTION OF A-DIHYDROBILINDIONE WITH NUCLEOPHILES AS A MODEL FOR PHYTOCHROME INTERCONVERSION

Krauss, Corinna; Bubenzer, C. und Scheer, Hugo (1979): STUDIES ON PLANT BILE PIGMENTS-6. PHOTOCHEMICALLY ASSISTED REACTION OF A-DIHYDROBILINDIONE WITH NUCLEOPHILES AS A MODEL FOR PHYTOCHROME INTERCONVERSION. In: Photochemistriy and Photobiology, Bd. 38: S. 473-477

Abstract

From the A-dihydrobilindione 3. the pyridinium derivatives 6a,b and analogues thereof have been obtained by a formal nucleophilic substitution. The reaction is rationalized as a photochemically assisted oxidation of 3 with a subsequent regioselective addition of pyridine at C-5. By thermolysis. 6a.b yields back the parent bilin 3, together with an oxidation product. The significance of the reaction with respect to the phytochrome interconversion is discussed.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Biologie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 570 Biowissenschaften; Biologie