Less sensitive oxygen-rich organic peroxides containing geminal hydroperoxy groups

Gamage, Nipuni-Dhanesha H.; Stiasny, Benedikt; Stierstorfer, Jörg; Martin, Philip D.; Klapötke, Thomas M. und Winter, Charles H. (2015): Less sensitive oxygen-rich organic peroxides containing geminal hydroperoxy groups. In: Chemical Communications, Bd. 51, Nr. 68: S. 13298-13300

Abstract

Tetranitratoethane (C2H2N4O12), which has an oxygen content of 70.1% was synthesized by nitration of monomeric glyoxal using N2O5 and purified by sublimation. Single crystals could be grown from CH2Cl2/pentane and were used to determine the structure by X-ray diffraction. Several energetic parameters and values were also established.

• Dokumententyp: Zeitschriftenartikel
• Publikationsform: Publisher's Version
• Fakultät: Chemie und Pharmazie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 1359-7345
• Bemerkung: First published online 20 Jul 2015
• Sprache: Englisch