Less sensitive oxygen-rich organic peroxides containing geminal hydroperoxy groups

Gamage, Nipuni-Dhanesha H.; Stiasny, Benedikt; Stierstorfer, Jörg; Martin, Philip D.; Klapötke, Thomas M. and Winter, Charles H. (2015): Less sensitive oxygen-rich organic peroxides containing geminal hydroperoxy groups. In: Chemical Communications, Vol. 51, No. 68: pp. 13298-13300

Abstract

Tetranitratoethane (C2H2N4O12), which has an oxygen content of 70.1% was synthesized by nitration of monomeric glyoxal using N2O5 and purified by sublimation. Single crystals could be grown from CH2Cl2/pentane and were used to determine the structure by X-ray diffraction. Several energetic parameters and values were also established.

• Item Type: Journal article
• Form of publication: Publisher's Version
• Faculties: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry
• ISSN: 1359-7345
• Annotation: First published online 20 Jul 2015
• Language: English