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Dhayalan, Vasudevan; Sämann, Christoph; Knochel, Paul (2015): Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes. In: Chemical Communications, Vol. 51, No. 15: pp. 3239-3242
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Abstract

Addition of functionalized aryl, heteroaryl or adamantyl zinc reagents to various nitroso-arenes in the presence of magnesium salts and LiCl in THF produces after a reductive work-up with FeCl2 and NaBH4 in ethanol the corresponding polyfunctional secondary amines in high yields.