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Kirst, Christin; Bode, Bela E.; Cordes, David B.; Nejman, Phillip S.; Slawin, Alexandra M. Z.; Karaghiosoff, Konstantin; Woollins, J. D. (2016): Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation. In: Dalton Transactions, Vol. 45, No. 15: pp. 6348-6351
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Abstract

A convenient synthesis route to 2,2′-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3˙+ was accessed easily through one-electron oxidation with NOBF4.