Klischies, Martina; Stöckigt, Joachim und Zenk, Meinhart H.
(1978):
Stereospecificity of cinnamyl alcohol dehydrogenase and synthesis of stereospecifically labelled coniferyl alcohol.
In: Phytochemistry, Bd. 17, Nr. 9: S. 1523-1525
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Vorschau
Abstract
Using horse liver alcohol dehydrogenase, stereospecifically tritiated (R)- and (S)-(γ-3H)-coniferyl alcohol was synthesized. Using both of these substrates it was demonstrated that cinnamyl alcohol dehydrogenase from lignifying Forsythia tissue specifically removes the pro-R-hydrogen atom of coniferyl alcohol in the oxidation to the aldehyde. This also means that in the reverse reaction the A-hydrogen of NADPH is transferred to the Re-site of coniferyl aldehyde.
Dokumententyp: | Zeitschriftenartikel |
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Keywords: | Forsythia suspensa; Oleaceae; cinnamyl alcohol oxido-reductase; cinnamyl alcohol; cinnamyl aldehydes; stereospecificity |
Fakultät: | Chemie und Pharmazie |
Themengebiete: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
URN: | urn:nbn:de:bvb:19-epub-3616-7 |
Dokumenten ID: | 3616 |
Datum der Veröffentlichung auf Open Access LMU: | 29. Apr. 2008, 11:42 |
Letzte Änderungen: | 04. Nov. 2020, 12:47 |