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Mayr, Herbert; Grubmüller, Bärbel and Halberstadt, Inge K. (1979): Orientation effects in reactions of allenyl cations with styrene. In: Tetrahedron Letters, Vol. 20, No. 20: pp. 1749-1752 [PDF, 200kB]


Allenyl cations, generated from allenyl or alkynyl halides and Ag+, attack styrene at the side chain or at the aromatic nucleus. The allenyl/alkynyl product ratio is dependent on the structure of the precursor halide except for highly substituted systems.

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