Synthesis of γ-lactones from alkenes employing p-methoxybenzyl chloride as +CH2---CO−2 equivalent

Bäuml, Englbert; Tscheschlok, Kai; Pock, Rudolf und Mayr, Herbert (1988): Synthesis of γ-lactones from alkenes employing p-methoxybenzyl chloride as +CH2---CO−2 equivalent. In: Tetrahedron Letters, Bd. 29, Nr. 52: S. 6925-6926

Abstract

The ZnCl2 catalyzed reaction of p-methoxybenzyl chloride with alkenes yields the 1:1 addition products 3, which are converted into the γ-lactones 4 via Ru(VIII) catalyzed oxidative degradation of the aromatic ring.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie