Comment of the use of dichloromethyl methyl ether as formylating agent

Brüggen, Uwe von der und Mayr, Herbert (1988): Comment of the use of dichloromethyl methyl ether as formylating agent. In: Chemische Berichte, Bd. 121, Nr. 1: S. 191-193

Abstract

In contrast to normal alkenes, dialkylacetylenes can be formylated with dichloromethyl methyl ether (1) in the presence of 1.2 equivalents of boron trichloride. A rationalisation for the different behaviour of alkenes and alkynes arises from the NMR specktroscopic investigation of the reaction intermediates.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• Signatur: Chem. 26 h-121,1-4