
Abstract
In contrast to normal alkenes, dialkylacetylenes can be formylated with dichloromethyl methyl ether (1) in the presence of 1.2 equivalents of boron trichloride. A rationalisation for the different behaviour of alkenes and alkynes arises from the NMR specktroscopic investigation of the reaction intermediates.
Item Type: | Journal article |
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Faculties: | Chemistry and Pharmacy |
Subjects: | 500 Science > 540 Chemistry |
URN: | urn:nbn:de:bvb:19-epub-3902-1 |
Signature: | Chem. 26 h-121,1-4 |
Item ID: | 3902 |
Date Deposited: | 19. May 2008, 12:18 |
Last Modified: | 04. Nov 2020, 12:47 |