Electrophilic attack at allylsilanes. A quantitative determination of the β-silyl effect

Mayr, Herbert und Pock, Rudolf (1986): Electrophilic attack at allylsilanes. A quantitative determination of the β-silyl effect. In: Tetrahedron, Bd. 42, Nr. 15: S. 4211-4214

Abstract

The relative reactivities of allylsilanes and alkenes towards diarylmethyl cations have been determined by competition experiments. Introduction of a β-trimethylsilyl group increases the reactivity of propene towards the diphenylmethyl cation by a factor of 30700.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie