
Abstract
The Lewis acid catalysed addition of the piperityl chlorides 6 to isoprene yields adduct 7, which undergoes a cis-stereoselective cyclisation to give the diastereoisomeric muurolene monohydrochlorides 8. Treatment with potassium tert-butoxide affords β- and γ2- muurolene 2.
Item Type: | Journal article |
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Faculties: | Chemistry and Pharmacy |
Subjects: | 500 Science > 540 Chemistry |
URN: | urn:nbn:de:bvb:19-epub-3923-8 |
Item ID: | 3923 |
Date Deposited: | 20. May 2008, 12:03 |
Last Modified: | 04. Nov 2020, 12:47 |