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Benischke, Andreas D.; Leroux, Marcel; Knoll, Irina; Knochel, Paul (2016): Iron-Catalyzed Acylation of Polyfunctionalized Aryl- and Benzylzinc Halides with Acid Chlorides. In: Organic Letters, Vol. 18, No. 15: pp. 3626-3629
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Abstract

FeCl2 (5 mol %) catalyzes a smooth and convenient acylation of functionalized arylzinc halides at 50 degrees C (2-4 h) and benzylic zinc chlorides at 25 degrees C (0.5-4 h) with a variety of acid chlorides leading to polyfunctionalized diaryl and aryl heteroaryl ketones.