Abstract
This Perspective describes general methods for the preparation of polyfunctional zinc organometallics and their use in Negishi cross-coupling reactions. Recent advances including new ligands and palladium catalysts are described. Related Negishi cross-coupling reactions involving Ni-, Cu-, Co-, and Fe-catalyzed cross-couplings are covered. The availability of a range of zinc organometallics combined with new efficient catalysts allows for efficient cross coupling reactions with various organic electrophiles under usually mild conditions.
| Dokumententyp: | Zeitschriftenartikel |
|---|---|
| Fakultät: | Chemie und Pharmazie > Department Chemie |
| Themengebiete: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| ISSN: | 2155-5435 |
| Sprache: | Englisch |
| Dokumenten ID: | 48224 |
| Datum der Veröffentlichung auf Open Access LMU: | 27. Apr. 2018, 08:15 |
| Letzte Änderungen: | 04. Nov. 2020, 13:25 |
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