| Flügel, Erik A.; Lau, Vincent W.-H.; Schlomberg, Hendrik; Glaum, Robert; Lotsch, Bettina V. (2016): Homonuclear Mixed-Valent Cobalt Imidazolate Framework for Oxygen-Evolution Electrocatalysis. In: Chemistry-A European Journal, Vol. 22, Nr. 11: S. 3676-3680 |
Volltext auf 'Open Access LMU' nicht verfügbar.
Abstract
Herein, the synthesis and characterization of the first mixed-valent, purely cobalt-based zeolitic imidazolate framework, (Co3Co2III)-Co-II(C3H3N2)(12) is presented. The material adopts the cubic garnet-type structure and combines high thermal stability of up to 350 degrees C with excellent chemical stability. Electrochemical characterization showed that the cobalt centres are redox active and efficiently support oxygen evolution, thus rendering this framework a potential candidate for single-site heterogeneous catalysis based on earth-abundant elements.
| Dokumententyp: | Zeitschriftenartikel |
|---|---|
| Fakultät: | Chemie und Pharmazie > Department Chemie |
| Themengebiete: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| ISSN: | 0947-6539 |
| Sprache: | Englisch |
| ID: | 48316 |
| Veröffentlicht am: | 27. Apr. 2018 08:15 |
| Letzte Änderungen: | 27. Apr. 2018 08:15 |
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