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Klapötke, Thomas M.; Krumm, Burkhard; Scharf, Regina (2016): Oxalyl Chloride and Hydrazide Based Energetic Polynitro Derivatives. In: European Journal of inorganic Chemistry, No. 19: pp. 3086-3093
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Several new compounds as potential high-energy dense oxidizers (HEDOs) were synthesized from the nitro alcohols 2,2,2-trinitroethanol and 3,3,3-trinitropropanol with oxalyl chloride and hydrazide. The materials were characterized thoroughly by spectroscopic methods, and some of their crystal structures were determined through X-ray diffraction. The energetic properties, thermal stabilities, and sensitivities of the oxalates, carbonyl azides, and imidodicarboxylate were determined. Furthermore, the enthalpies of all compounds were calculated, and their energetic performances were explored with the EXPLO5 code.