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Böttcher, Hans-Christian; Mayer, Peter (2016): Synthesis and Molecular Structure of trans-[RhCl(NO)(PtBu2H)(2)]BF4. In: Zeitschrift für Anorganische und Allgemeine Chemie, Vol. 642, No. 4: pp. 299-301
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The synthesis and structural characterization of trans-[RhCl(NO)(PtBu2H)(2)]BF4 (2) is reported. The title compound could easily be prepared in good yields by a kind of bridge-splitting reaction of [{Rh(-Cl)(PtBu2H)(2)}(2)] (1) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 2 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.