Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4

Böttcher, Hans-Christian; Mies, Thomas und Mayer, Peter (2016): Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4. In: Zeitschrift für Anorganische und Allgemeine Chemie, Bd. 642, Nr. 14: S. 793-795

Abstract

The synthesis and structural characterization of trans-[IrCl(NO)(PtBu2H)(2)]BF4 (1) is reported. The title compound was prepared in good yield in the reaction of in situ-prepared trans-[IrCl(coe)(PtBu2H)(2)] (coe = cis-cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0044-2313
• Sprache: Englisch