Abstract
The synthesis and structural characterization of trans-[IrCl(NO)(PtBu2H)(2)]BF4 (1) is reported. The title compound was prepared in good yield in the reaction of in situ-prepared trans-[IrCl(coe)(PtBu2H)(2)] (coe = cis-cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.
Item Type: | Journal article |
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Faculties: | Chemistry and Pharmacy > Department of Chemistry |
Subjects: | 500 Science > 540 Chemistry |
ISSN: | 0044-2313 |
Language: | English |
Item ID: | 48376 |
Date Deposited: | 27. Apr 2018, 08:15 |
Last Modified: | 04. Nov 2020, 13:26 |