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Böttcher, Hans-Christian; Mies, Thomas; Mayer, Peter (2016): Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)(2)]BF4. In: Zeitschrift für Anorganische und Allgemeine Chemie, Vol. 642, No. 14: pp. 793-795
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Abstract

The synthesis and structural characterization of trans-[IrCl(NO)(PtBu2H)(2)]BF4 (1) is reported. The title compound was prepared in good yield in the reaction of in situ-prepared trans-[IrCl(coe)(PtBu2H)(2)] (coe = cis-cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.