The Nucleophilicity of Persistent -Monofluoromethide Anions

Zhang, Zhe; Puente, Ángel; Wang, Fang; Rahm, Martin; Mei, Yuncai; Mayr, Herbert und Prakash, G. K. Surya (2016): The Nucleophilicity of Persistent -Monofluoromethide Anions. In: Angewandte Chemie-international Edition, Bd. 55, Nr. 41: S. 12845-12849

Abstract

-Fluorocarbanions are key intermediates in nucleophilic fluoroalkylation reactions. Although frequently discussed, the origin of the fluorine effect on the reactivity of -fluorinated CH acids has remained largely unexplored. We have now investigated the k

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 1433-7851
• Sprache: Englisch