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Zhang, Zhe; Puente, Ángel; Wang, Fang; Rahm, Martin; Mei, Yuncai; Mayr, Herbert; Prakash, G. K. Surya (2016): The Nucleophilicity of Persistent -Monofluoromethide Anions. In: Angewandte Chemie-international Edition, Vol. 55, No. 41: pp. 12845-12849
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Abstract

-Fluorocarbanions are key intermediates in nucleophilic fluoroalkylation reactions. Although frequently discussed, the origin of the fluorine effect on the reactivity of -fluorinated CH acids has remained largely unexplored. We have now investigated the k