Baumann, Andreas N.; Music, Arif; Karaghiosoff, Konstantin and Didier, Dorian
(2016):
Highly diastereoselective approach to methylenecyclopropanes via boron-homologation/allylboration sequences.
In: Chemical Communications, Vol. 52, No. 12: pp. 2529-2532
DOI: 10.1039/c5cc09904h
Abstract
A simple and efficient diastereoselective synthesis of methylenecyclopropanes is described, in which boron-homologation and allylboration are merged into a one-pot process, starting from in situ generated cyclopropenyllithium species. This unprecedented methodology opens a new route to strained alkylidenecycloalkanes containing a quaternary stereocenter, in high yields and excellent diastereomeric ratios.
| Item Type: | Journal article |
|---|---|
| Faculties: | Chemistry and Pharmacy > Department of Chemistry |
| Subjects: | 500 Science > 540 Chemistry |
| ISSN: | 1359-7345 |
| Language: | English |
| Item ID: | 48494 |
| Date Deposited: | 27. Apr 2018, 08:15 |
| Last Modified: | 26. Oct 2021, 12:38 |
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