From benzodithiophene to diethoxy-benzodithiophene covalent organic frameworks - structural investigations

Lohse, Maria S.; Rotter, Julian M.; Margraf, Johannes T.; Werner, Veronika; Becker, Matthias; Herbert, Simon; Knochel, Paul; Clark, Timothy; Bein, Thomas und Medina, Dana D. (2016): From benzodithiophene to diethoxy-benzodithiophene covalent organic frameworks - structural investigations. In: Crystengcomm, Bd. 18, Nr. 23: S. 4295-4302

Abstract

The incorporation of side groups into a covalent organic framework (COF) backbone can be of significant importance for developing new frameworks with enhanced properties. Here we present a novel pi-stacked thiophene-based COF containing a benzodithiophene building unit modified with ethoxy side chains. The resulting BDT-OEt COF is a crystalline mesoporous material featuring high surface area and accessible hexagonal pores. We further synthesized a series of COFs containing both BDT and BDT-OEt building units at different ratios. The impact of the gradual incorporation of the BDT-OEt building units into the COF backbone on the crystallinity and porosity was investigated. Furthermore, molecular dynamic simulations shed light on the possible processes governing the COF assembly from molecular building blocks.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie ; Physik
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie ; 500 Naturwissenschaften und Mathematik > 530 Physik
• ISSN: 1466-8033
• Sprache: Englisch