Synthesis and characterisation of the porous zinc phosphonate [Zn₂(H₂PPB)(H₂O)₂]center dot xH₂O

Hermer, N.; Reinsch, H.; Mayer, P. and Stock, N. (2016): Synthesis and characterisation of the porous zinc phosphonate [Zn₂(H₂PPB)(H₂O)₂]center dot xH₂O. In: Crystengcomm, Vol. 18, No. 42: pp. 8147-8150

Abstract

The synthesis, structure and properties of the new microporous zinc phosphonate [Zn-2(H2PPB)(H2O)2]center dot xH(2)O (denoted as CAU-25, CAU stands for Christian-Albrechts-University) are presented. The crystal structure was determined by combining single crystal and powder X-ray diffraction data. The final refinement was carried out by using the Rietveld method. The structure contains one-dimensional channels between dense, corrugated, hydrogen bonded layers with a diameter of approximately 5 angstrom. While N-2 uptake was not observed at 77 K, CO2 and H2O uptakes were measured at 298 K.

• Item Type: Journal article
• Faculties: Chemistry and Pharmacy > Department of Chemistry
• Subjects: 500 Science > 540 Chemistry
• ISSN: 1466-8033
• Language: English