Komplexchemie perhalogenierter Cyclopentadiene und Alkine

Sünkel, Karlheinz und Motz, Doris (1988): Komplexchemie perhalogenierter Cyclopentadiene und Alkine. I. Metallierung von (C5Cl4Br)Mn(CO)3 und Umsetzungen mit Elektrophilen. In: Chemische Berichte, Vol. 121, No. 4: pp. 799-801

Abstract

Coordination Chemistry of Perhalogenated cyclopentadienes and Alkynes, I. - metalation of (C5Cl4Br)Mn(CO)3 and Reactions with Electrophiles Lithiation of (C5Cl4Br)Mn(CO)3 with n-butyllithium gives the isolable, but very air-sensitive (C5Cl4Li)Mn(CO)3 (2), which reacts with a series of electrophiles to yield (C5Cl4Br)Mn(CO)3 (3), where E = H, Me, SiR3, CO2R or SR.

• Item Type: Journal article
• Faculties: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry
• Signature: Chem. 26 h-121,1-4