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Sünkel, Karlheinz and Motz, Doris (1988): Komplexchemie perhalogenierter Cyclopentadiene und Alkine. I. Metallierung von (C5Cl4Br)Mn(CO)3 und Umsetzungen mit Elektrophilen. In: Chemische Berichte, Vol. 121, No. 4: pp. 799-801 [PDF, 18MB]

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Abstract

Coordination Chemistry of Perhalogenated cyclopentadienes and Alkynes, I. - metalation of (C5Cl4Br)Mn(CO)3 and Reactions with Electrophiles Lithiation of (C5Cl4Br)Mn(CO)3 with n-butyllithium gives the isolable, but very air-sensitive (C5Cl4Li)Mn(CO)3 (2), which reacts with a series of electrophiles to yield (C5Cl4Br)Mn(CO)3 (3), where E = H, Me, SiR3, CO2R or SR.

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