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Sünkel, Karlheinz (1988): Komplexchemie perhalogenierter Cyclopentadiene und Alkine. III. Reaktion von Pt(PPh3)2(C2H4) mit Monofluoracetylen und Dichloracetylen. Kristallstruktur von Pt(PPh3)2(Cl)(CCCl). In: Journal of Organometallic Chemistry, Bd. 348, Nr. 1: C12-C14 [PDF, 150kB]

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Abstract

Pt(PPh3)2(C2H4) reacts with monofluoroacetylene to give the π-complex Pt(PPh3)2(FCCH), and with dichloroacetylene under oxidative addition to yield Pt(PPh3)2(Cl)(ClCCl), the structure of which was determined by X-ray crystallography.

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